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DJPS

Diyala Journal For Pure Science

Scientific Refereed Journal Published By College of Science - University of Diyala

 

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djps.1304.338A

Diyala Journal For Pure Sciences DJPS

ISRA Impact Factor:3.715

P- ISSN:2222-8373, E-ISSN:2518-9255

Volume 13, Issue 4, Part 1 , October. 2017

 

 

Synthesis and Characterization of Co (II), Ni (II), Cu (II), and Pd(II) Complexes with mono sodium 2,4,6-trioxotetrahydropyrimidine-1(2H)-carbodithioate

 

Anwar Adil Hameed

 

Year: 2017, Volume: 13, Issue: 4, Part:1

 

Pages: 208-222 , DOI: http://dx.doi.org/10.24237/djps.1304.338A

 

Language: English

 

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Abstract


 

Mono sodium 2,4,6-trioxotetrahydropyrimidine-1(2H)-carbodithioate (L) was prepared from barbituric acid with carbon disulfide (CS2) in the presence of sodium hydroxide, then reacted with some chloride metals to synthesis a complexes of the types [M (L) Cl (H2O)3], [M (L)2(H2O) 2] and [M(L)2] {M= Co(II), Ni(II), Cu(II)}, and [Pd (L)(H2O)2]Cl and[Pd (L)2] . These compounds were characterized using infra-red spectra FTIR, electronic spectra UV–VIS, proton nuclear magnetic resonance 1H-NMR spectroscopy, Micro Elemental Analysis, and Magnetic Measurements.These measurements indicate that the prepared complexes have octahedral, square planer or tetrahedral geometry. Molar Conductance measurements shows all the prepared complexes are non-electrolytic except the palladium complex of the type [Pd(L)(H2O)2]Cl.

 

Keywords: Barbituric acid, carbon disulfide, carbodithioate.

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